The title compound, C 10 H 8 N 2 O 2 , consisting of a benzene ring with two OÐCH 2 ÐCN ortho substituents, has approximately C 2 symmetry. The supramolecular structure of the compound is determined by two hydrogen bonds and two %±% stacking interactions.
2-(Cyanomethoxy)benzonitrile
✍ Scribed by Narasimhamurthy, T. ;Shashidhar, ;Shivashankar, S. A. ;Vittala Reddy, P. ;Rathore, R. S.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 390 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 9 H 8 N 2 O, was synthesized from 2-cyanoaniline and acetyl chloride in dry acetone. The crystal structure is stabilized by an intramolecular C-HÁ Á ÁO hydrogen-bond contact, which forms a six-membered ring, and two intermolecular N-HÁ Á ÁN and C-HÁ Á ÁO hydrogen bonds.
Phenyhnagnesium bromide and methyhnagnesium bromide in tetmhydrofuran undergo a regiose lective addition to the cyan0 group of the two title compounds. Phenyllithium and methyllithhnn add selectively to the azomethine portion of 2-[(benzylidene)anko]benzonitrile, but to the cyano group of Z[(dipheny
The molecule of the title compound, C 30 H 26 N 4 , is non-planar. The dihedral angles between the two benzene rings of the benzyl groups, and between the benzimidazole and 4-(methyl)benzonitrile ring systems, are 117.9 (2) and 70.3 (3) , respectively. The bond distances and angles are all in normal