2-Acetamidobenzonitrile
✍ Scribed by Arslan, Burcu ;Kazak, Canan ;Kirilmis, Cumhur ;Koca, Murat ;Büyükgüngör, Orhan
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 129 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 9 H 8 N 2 O, was synthesized from 2-cyanoaniline and acetyl chloride in dry acetone. The crystal structure is stabilized by an intramolecular C-HÁ Á ÁO hydrogen-bond contact, which forms a six-membered ring, and two intermolecular N-HÁ Á ÁN and C-HÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
A new approach towards simple aldonic acid derivatives starting from the corresponding aldoses via the 2-acetamido-2-deoxy formazans resulted in the synthesis of 2-acetamido-2-deoxy-o-galactono-1,4lactone (81, and its 6-deoxy (11) and 6-azido-6-deoxy ( 14) analogues on treatment with trifluoroacetic
Phenyhnagnesium bromide and methyhnagnesium bromide in tetmhydrofuran undergo a regiose lective addition to the cyan0 group of the two title compounds. Phenyllithium and methyllithhnn add selectively to the azomethine portion of 2-[(benzylidene)anko]benzonitrile, but to the cyano group of Z[(dipheny