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2-Cyano-N-(di­phenyl­methyl­ene)­benzen­amine

✍ Scribed by Usman, Anwar ;Razak, Ibrahim Abdul ;Fun, Hoong-Kun ;Chantrapromma, Suchada ;Tian, Jing-Zhi ;Zhang, Yan ;Xu, Jian-Hua

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
212 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, C 20 H 14 N 2 , the orientations of the three aromatic rings are determined by the sp 2 state of the two central N and C atoms. The crystal packing of the title compound is stabilized by weak CÐHÁ Á Á% interactions.

📜 SIMILAR VOLUMES

N-(1,2-Di­phenyl-2-oxoethyl­idene)­benze
N-(1,2-Di­phenyl-2-oxoethyl­idene)­benzen­amine N-oxide
✍ Usman, Anwar ;Fun, Hoong-Kun ;Hu, Hua-You ;Xu, Jian-Hua 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 247 KB

The title compound, C 20 H 15 NO 2 , crystallizes in a monoclinic unit cell with two independent molecules in the asymmetric unit. The con®gurations of three phenyl rings are determined by the sp 2 C and N atoms of the ethylideneamine group.

Di­methyl N,N′-(1,2-phenyl­ene)­dicarbam
Di­methyl N,N′-(1,2-phenyl­ene)­dicarbamate
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4-(N,N-Di­methyl­amino­methyl­ene)-2-phe
4-(N,N-Di­methyl­amino­methyl­ene)-2-phenyl-2-oxazolin-5-one
✍ Vasuki, G. ;Thamotharan, S. ;Ramamurthi, K. ;Ambika, S. ;Singh, R. M. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 180 KB

The title compound, C 12 H 12 N 2 O 2 , crystallizes in the triclinic space group P1 with two crystallographically independent molecules in the asymmetric unit. These two molecules differ slightly in the relative orientation of the phenyl and oxazoline rings. The molecular packing in the crystal is

2-[2-(2,6-Di­methyl­phenyl­amino)­phenyl
2-[2-(2,6-Di­methyl­phenyl­amino)­phenyl­methyl­ene­amino]-1,3-diiso­propyl­benzene
✍ Gao, Haiyang ;Wu, Qing ;Ng, Seik Weng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 176 KB

The ortho-disubstituted aromatic ring in the title compound, C 27 H 32 N 2 , is twisted by 76.1 (1) with respect to the isopropylsubstituted ring and by 89.3 (1) with respect to the methylsubstituted ring. The amino N atom is linked intramolecularly to the imino N by a hydrogen bond [NÁ Á ÁN = 2.686