The title compound, C 22 H 26 N 2 O 4 , was prepared by reaction of trans-1,2-cyclohexanediamine and 2-hydroxy-3-methoxybenzaldehyde. The molecular structure is stabilized by intramolecular O-HÁ Á ÁN hydrogen bonds.
2-Chloro-(3-methoxysalicylidene)aniline
✍ Scribed by Francis, Savarimuthu ;Muthiah, Packianathan Thomas ;Venkatachalam, Galmari ;Ramesh, Rengan
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 239 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
An almost planar conformation exhibited by the title molecule, C 14 H 12 ClNO 2 , is stabilized by an intramolecular OÐHÁ Á ÁN hydrogen bond, which forms a ring of graph-set motif S(6). In the crystal structure, %±% and CÐHÁ Á Á% interactions involving both the aromatic rings form twodimensional networks.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.042 wR factor = 0.132 Data-to-parameter ratio = 10.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The molecular structure of the title compound, (I), shown with 50% probability displacement ellipsoids.