2-Phenylethylammonium bromide, C 8 H 12 N + ÁBr À , adopts a layered structure consisting of alternating hydrophilic and hydrophobic regions. The ammonium groups and bromide anions interact through N + -HÁ Á ÁBr À hydrogen bonds, forming transoid one-dimensional ladders, which are further linked by
2-Chloro-2-phenylethylammonium chloride
✍ Scribed by Lejon, Tore ;Ingebrigtsen, Truls ;Hansen, Lars Kr.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 98 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 8 H 11 ClN + ÁCl À , has been obtained as an intermediate in the synthesis of 2-phenylaziridine. There are two molecules in the asymmetric unit and these are linked in the crystal structure by a network of intermolecular N-HÁ Á ÁCl and C-HÁ Á ÁCl hydrogen bonds, plus an intermolecular ClÁ Á ÁCl interaction.
📜 SIMILAR VOLUMES
The crystal structure of the title compound, {(C~8~H~12~N)[HgCl~3~]}~__n__~, exhibits alternating organic and inorganic layers, which interact __via__ N—H...Cl hydrogen bonding. In the inorganic layer, an infinite one-dimensional anion chain is formed by [HgCl~3~]^−^ subunits.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.029 A Ê R factor = 0.051 wR factor = 0.132 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.034 wR factor = 0.103 Data-to-parameter ratio = 13.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.