The title compound, C 8 H 11 ClN + ÁCl À , has been obtained as an intermediate in the synthesis of 2-phenylaziridine. There are two molecules in the asymmetric unit and these are linked in the crystal structure by a network of intermolecular N-HÁ Á ÁCl and C-HÁ Á ÁCl hydrogen bonds, plus an intermo
2-Phenylethylammonium bromide
✍ Scribed by Rademeyer, Melanie
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 248 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
2-Phenylethylammonium bromide, C 8 H 12 N + ÁBr À , adopts a layered structure consisting of alternating hydrophilic and hydrophobic regions. The ammonium groups and bromide anions interact through N + -HÁ Á ÁBr À hydrogen bonds, forming transoid one-dimensional ladders, which are further linked by electrostatic N + Á Á ÁBr À interactions into twodimensional sheets.
📜 SIMILAR VOLUMES
The title compound, C 4 H 12 N + ÁBr À , is a hydrolysis product of the 1-(dibromoboryl)ferrocene±dimethylethylamine (1/1) adduct. The metric symmetry is apparently orthorhombic Ccentred, but the intensity statistics indicate unambigously the correct Laue symmetry, viz. primitive monoclinic. The eth
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.029 A Ê R factor = 0.051 wR factor = 0.132 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The crystal structure of a new polymorph of the title compound, C 8 H 12 N + ÁC 10 H 11 O 2 À , was solved by simulated annealing from laboratory X-ray powder diffraction data, collected at 295 K. Subsequent Rietveld refinement using data collected to 1.54 A ˚resolution yielded an R wp of 0.029. The