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2-Chloro-1,1,1-Triethoxyethane and its Use in a Versatile Synthesis of Substituted, 2-Chloromethyl Heterocycles Including Benzothiazole and Benzoxazole

✍ Scribed by Mylari, Banavara L.; Scott, Pamela J.; Zembrowski, William J.


Book ID
120015581
Publisher
Taylor and Francis Group
Year
1989
Tongue
English
Weight
146 KB
Volume
19
Category
Article
ISSN
0039-7911

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## Abstract The pyrrolate ion **(5)** is shown to produce __N, N__′‐dipyrrolyl methane **(4)** when reacted with dichloromethane under conditions of weak counter‐ion association. 1‐Azoniafulvene ion **(13)** is suggested to be the key intermediate in this reaction. __N, N__′‐Dipyrrolyl methane **(4