The title compound, also known as 7-iodotropolone, C~7~H~5~IO~2~, exists in the crystalline state as the 2-hydroxy-7-iodocyclohepta-2,4,6-trien-1-one tautomer and not as 2-hydroxy-3-iodocyclohepta-2,4,6-trien-1-one. There is a bifurcated O—H...O bond with two acceptor O atoms. One of these acceptors
2-Amino-5-[4-(octylamino)phenyl]cyclohepta-2,4,6-trien-1-one
✍ Scribed by Kubo, Kanji ;Matsumoto, Taisuke ;Katahira, Kouki ;Mori, Akira
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 190 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, also known as 2-amino-5-[4-(octylamino)phenyl]tropone, C 21 H 28 N 2 O, contains two crystallographically independent molecules in the asymmetric unit. The NH 2 group of the 2-aminotropone unit and the NH group of the aminobenzene unit participate in intermolecular hydrogen bonding with the O atoms of neighbouring molecules. An intermolecularinteraction is observed in the crystal structure.
📜 SIMILAR VOLUMES
The title compound, C 23 H 26 BrN 5 O 2 , was synthesized by the reaction of 4- [(2,6-dimethylphenyl)aminocarbonylmethyl]piperazine and 3-(3-nitrophenyl)-5-chloromethyl-1,2,4-oxadiazole. There are intramolecular C-HÁ Á ÁN and intermolecular N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds in the crystal struc
The title compound, C 23 H 26 ClN 5 O 2 , was synthesized by the reaction of 4- [(2,6-dimethylphenyl)aminocarbonylmethyl]piperazine and 5-chloromethyl-3-(2-chlorophenyl)-1,2,4oxadiazole. In the structure, there are intramolecular C-HÁ Á ÁN, N-HÁ Á ÁN and C-HÁ Á ÁO hydrogen bonds, and intermolecular
The two benzene rings of the title compound, C 18 H 20 O 5 , are almost parallel, with a dihedral angle of 1.3 (2) . The hydroxy group forms intermolecular O-HÁ Á ÁO hydrogen bonds which link the molecules into infinite chains along the c axis.