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3-Hydroxy­tropolone (2,7-dihydroxy­cyclo­hepta-2,4,6-trien-1-one)

✍ Scribed by Kubo, Kanji ;Matsumoto, Taisuke ;Mori, Akira


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
211 KB
Volume
63
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES


2-Hydr­oxy-7-iodo­cyclo­hepta-2,4,6-trie
✍ Kubo, Kanji ;Matsumoto, Taisuke ;Mori, Akira 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 234 KB

The title compound, also known as 7-iodotropolone, C~7~H~5~IO~2~, exists in the crystalline state as the 2-hydroxy-7-iodocyclohepta-2,4,6-trien-1-one tautomer and not as 2-hydroxy-3-iodocyclohepta-2,4,6-trien-1-one. There is a bifurcated O—H...O bond with two acceptor O atoms. One of these acceptors

2-Amino-5-[4-(octylamino)phen­yl]cyclo­h
✍ Kubo, Kanji ;Matsumoto, Taisuke ;Katahira, Kouki ;Mori, Akira 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 190 KB

The title compound, also known as 2-amino-5-[4-(octylamino)phenyl]tropone, C 21 H 28 N 2 O, contains two crystallographically independent molecules in the asymmetric unit. The NH 2 group of the 2-aminotropone unit and the NH group of the aminobenzene unit participate in intermolecular hydrogen bondi

Dimers of 3,7-dehydrotropones (bicyclo[3
✍ Barbara Szechner; Max Rey; André S. Dreiding; Rita Grieb 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 678 KB

## Abstract 2‐(__tert__‐Butyl)‐3,7‐dehydrotropone (7‐(__tert__‐butyl)bicyclo[3.2.0]hepta‐1(7),2,4‐trien‐6‐one; **1**) was found to dimerize reversibly to **2A** by [2 + 4]‐cycloaddition/cycloreversion reaction. The equilibrium lies on the side of the highly strained dimer **2A** in the solid state,