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2-(4-Chloro­phenyl)-1H-benzimidazole

✍ Scribed by Jian, Fang-Fang ;Yu, Huan-Qing ;Qiao, Yuan-Biao ;Zhao, Pu-Su ;Xiao, Hai-Lian


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
113 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the title compound, C 20 H 14 Cl 2 N 2 , the dihedral angles formed by the benzimidazole ring with the benzene rings of the 4-chlorobenzyl and the 4-chlorophenyl groups are 88.15 (8) and 33.4 (1) , respectively. The molecules are linked by C-HÁ Á ÁCl hydrogen bonds, forming a C(12) chain along th

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In the title compound, C~13~H~9~BrN~2~, the dihedral angle between the benzimidazole and benzene ring systems is 26.71 (9) Å. The molecules are linked by intermolecular N—H...N hydrogen bonds to form infinite chains parallel to the __b__ axis.

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In the title compound, C~13~H~9~FN~2~, the dihedral angle between the benzimidazole and benzene ring systems is 29.2 (1) Å. The molecules are linked by intermolecular N—H...N hydrogen bonds to form infinite chains parallel to the __b__ axis.

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The title compound, C 14 H 10 ClNO, is a nitrogen derivative closely related to natural 3 0 ,7-epoxy-8,4 0 -oxyneolignans, which are of interest because of their cytotoxic activity. Centrosymmetric hydrogen bonding occurs between pairs of molecules.