𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2-(3-Nitro­phen­yl)-2-oxazoline

✍ Scribed by Decken, Andreas ;Botelho, Laura ;Sadowy, Amber L. ;Yadav, Paras N. ;Gossage, Robert A.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
102 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C 9 H 8 N 2 O 3 , was obtained by a zinc chloride-promoted addition and ring-closure reaction involving 3-nitrobenzonitrile and 2-ethanolamine. The planar oxazoline and aromatic rings of the molecule are almost coplanar, with a dihedral angle of 8.79 (5) between them. The oxazoline ring is disordered over two positions, rendering the oxygen and nitrogen positions indistinguishable.

📜 SIMILAR VOLUMES

2-(2-Methyl-3-nitro­phen­yl)acetic acid
2-(2-Methyl-3-nitro­phen­yl)acetic acid
✍ Lu, Ai-Hua ;Wang, Jun-Ping ;Chen, You-Sheng ;Jia, Hong-Sheng ;Ma, Hong-Fei 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 146 KB

In the crystal structure of the title compound, C 9 H 9 NO 4 , intermolecular O-HÁ Á ÁO hydrogen bonds link the molecules into centrosymmetric dimers.

Acetone (2-nitro­phen­yl)hydrazone
Acetone (2-nitro­phen­yl)hydrazone
✍ Jian, Fang-Fang ;Zhuang, Rui-Rui ;Wang, Ke-Fei ;Zhao, Pu-Su ;Xiao, Hai-Lian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 63 KB

The title compound, C 9 H 11 N 3 O 2 , was prepared by the reaction of 1-(2-nitrophenyl)hydrazine with acetone at room temperature. The molecule is approximately planar and exhibits a weak intramolecular hydrogen-bond interaction.