The title compound, C 15 H 12 N 2 O 3 , is non-planar, with a dihedral angle of 83.0 (1) between the two benzene rings. The molecules are linked into a ribbon along the b axis by intermolecular C-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds. The packing is further stabilized by C-HÁ Á Á andinteractions.
N-(2-Methylphenyl)-N-[3-(2-nitrophenyl)prop-2-enylidene]amine
✍ Scribed by Yang, Xiao-Yan ;Li, Ying ;Li, Xue-Mei ;Zhang, Shu-Sheng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 105 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the crystal structure of the title complex, C 21 H 21 N, the molecule lies on a twofold rotation axis. The N atom is sp 2 hybridized. Comparisons are made with similar compounds in this series.
The geometrical parameters for the title compound, C 16 H 13 NO 2 S, are normal. The non-centrosymmetric crystal packing, which is consistent with the non-zero second harmonic generation response, may be influenced by a weak intermolecular C-HÁ Á ÁO interaction.
In the title compound, C~17~H~12~ClN~3~O~5~, the benzene rings are twisted out of the central –C~ar~–C–C(–CN)–C(=O)–N–plane. The dihedral angles between this plane and the aromatic planes are 31.2 (4) and 4.8 (3)°. The C=C double bond is in an __E__ configuration.