2-[2′-(Phenylsulfonyl)ethyl]cyclopentanone
✍ Scribed by Loughlin, Wendy A. ;McCleary, Michelle A. ;Healy, Peter C.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 224 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The structure of the title compound, C 13 H 16 O 3 S, prepared by the reaction of the lithium enolate of cyclopentanone with phenylvinyl sulfoxide and subsequent oxidation with m-chloroperoxybenzoic acid (m-CPBA), shows the phenylsulfonylethyl side chain to be bonded to the cyclopentanone ring in a pseudo-equatorial orientation.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.017 A Ê R factor = 0.111 wR factor = 0.301 Data-to-parameter ratio = 12.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 16 H 13 NO 4 S, the phthalimide ring system makes a dihedral angle of 56.7 (1) with the phenyl ring.
In the title compound, C 16 H 14 N 2 O 4 S, the phenyl and quinoxaline 1,4-dioxide planes are approximately perpendicular, with a dihedral angle of 85.8 (2) .
In the title molecule, C 35 H 27 NO 3 S 2 , the indole system is approximately planar. The phenyl rings of the phenylsulfonyl and phenylsulfanyl groups are oriented at angles of 74.69 (7) and 88.35 (9) , respectively, to the indole ring system. The dihedral angle between the two phenyl rings of the
Mo K radiation = 0.17 mm À1 T = 295 (2) K 0.26 Â 0.18 Â 0.14 mm ## Data collection Bruker Kappa APEX2 diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1996) T min = 0.892, T max = 0.976 29408 measured reflections 6381 independent reflections 4267 reflections with I > 2(I) R in