The structure of the title compound, C 13 H 16 O 3 S, prepared by the reaction of the lithium enolate of cyclopentanone with phenylvinyl sulfoxide and subsequent oxidation with m-chloroperoxybenzoic acid (m-CPBA), shows the phenylsulfonylethyl side chain to be bonded to the cyclopentanone ring in a
2,6-Dimethyl-2-[2′-(phenylsulfonyl)ethyl]cyclohexanone
✍ Scribed by Loughlin, Wendy A. ;McCleary, Michelle A. ;Healy, Peter C.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 257 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 25 H 26 O 2 , was isolated and characterized as a stable intermediate in the conversion of 2,2-diphenylethyl 2,4,6-trimethylphenyl ketone to its formaldehyde-derived enone.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.047 wR factor = 0.131 Data-to-parameter ratio = 19.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.010 A Ê Disorder in main residue R factor = 0.043 wR factor = 0.152 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.