The title compound, C 15 H 11 ClN 2 S, has been prepared by the reaction of Lawesson's reagent with N-(2-chlorobenzoyl)-N H -(4-methylbenzoyl)hydrazine, under microwave irradiation and in the absence of solvent. It crystallizes with two molecules per asymmetric unit and X-ray analysis reveals that t
2-[2-(p-Chlorophenyl)benzimidazol-1-ylmethyl]-5-(2-fluoroanilino)-1,3,4-thiadiazole
✍ Scribed by Kaynak, F. Betül
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 159 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C~12~H~9~ClN~4~OS~2~, was synthesized __via__ condensation of 5-chloromethyl-3-(4-chlorophenyl)-1,2,4-oxadiazole with 5-mercapto-2-methyl-1,3,4-thiadiazole. The benzene and oxadiazole rings are coplanar due to the extended aromatic system. The angle between this plane and the thi
The molecule of the title compound, C 30 H 26 N 4 , is non-planar. The dihedral angles between the two benzene rings of the benzyl groups, and between the benzimidazole and 4-(methyl)benzonitrile ring systems, are 117.9 (2) and 70.3 (3) , respectively. The bond distances and angles are all in normal
In the title compound, C 20 H 14 Cl 2 N 2 , the dihedral angles formed by the benzimidazole ring with the benzene rings of the 4-chlorobenzyl and the 4-chlorophenyl groups are 88.15 (8) and 33.4 (1) , respectively. The molecules are linked by C-HÁ Á ÁCl hydrogen bonds, forming a C(12) chain along th