The title compound, C~26~H~26~N~2~O~7~, is a thiamidine derivative. Geometric parameters are in the usual ranges. The crystal packing is stabilized by a classical N—H...O hydrogen bond, several weak C—H...O hydrogen bonds and a π–π stacking interaction.
(1S,2S)-2-[(3R,4S)-3-Methyl-4-phenyl-1,2,3,4-tetrahydroisoquinolin-2-yl]cyclohexanol
✍ Scribed by Ben Ali, Karim ;Chiaroni, Angèle ;Bohe, Luis
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 142 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the sugar molecule of the title compound, C~104~H~94~O~11~·CH~4~O·0.75C~4~H~8~O, the pyranose ring adopts the expected chair conformation. Weak intra- and intermolecular C—H...O hydrogen bonds, in part, control the molecular conformation and stabilize the crystal structure.
The relative con®guration of the title compound, C 18 H 27 NO 4 , was determined as being R,S,S,S. There are three crystallographically independent molecules in the asymmetric unit, which show only slight conformational differences. Molecules in the crystal structure are connected by hydrogen bonds