1H CIDNP study of the photoinduced electron transfer reaction between trans-stilbene and triethylamine
โ Scribed by Heino Klaukien; Manfred Lehnig
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 378 KB
- Volume
- 84
- Category
- Article
- ISSN
- 1010-6030
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๐ SIMILAR VOLUMES
## Abstract The title reaction was studied in different waterโcosolvent (methanol) mixtures. The results have been rationalized employing the MarcusโHush treatment. To apply this treatment, the true, unimolecular, electronโtransfer rate constants (__k__~et~) were obtained from the experimentally me
## Kinetics and Stereoselectivity of the Inner-sphere Electron-Transfer Reaction between [Co(bamap)H,Or (bamap = 2,6-Bis(3-carboxy-l,2-dimethyl-2-azapropyl)pyridine) and Optically Active Iron(I1) Complexes
Based on an activation model, a available scheme to calculate the rate of the electron-transfer reaction between transition-metal complexes in aqueous solution is presented. Ab initio technique is used to determine the electron-transfer reactivity of the type M(H 2 O) 2+/3+ 6 of transition-metal com