The thermodynamic criterion or reversible electron phototransfer correlates with CIDNP effects in sensitized trans-cis photoisome~tion ol fumaronitrile in aoetonirrile. It tallows from CIDNP analysis xhat rhc free radical anion OF FIJITIWOII~~~~~C does no1 undergo geometrial isomerization
1H CIDNP study of the role of radical ions in the cis-trans isomerization of stilbenes in the presence of electron donors and acceptors
β Scribed by A.I. Kruppa; O.I. Mikhailovskaya; T.V. Leshina
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 467 KB
- Volume
- 147
- Category
- Article
- ISSN
- 0009-2614
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The ESR spectra of radical cations of cis-and trans-deealin have been recorded in different halocarbon matrices within the temperature range 4.2 IO 130 K. The ground-state structures of both isomers have been calculated using the UHF/MNDO technique and found to be 'As or ZB, for transdecalin+ and 'A
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