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1H and 31P NMR spectra of the phenyl ester of dichlorophosphoric acid in a nematic phase

✍ Scribed by J. Hansen; J. P. Jacobsen

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 375 KB
Volume: 15
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270150108

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✦ Synopsis

Abstract

The ^1^H and ^31^P NMR spectra of the phenyl ester of dichlorophosphoric acid dissolved in Merck nematic phase IV have been recorded and analysed. The values of the dipole dipole couplings have been discussed in terms of several different geometric models. Non‐planarity of C‐1, O, P and the phenyl ring must be assumed in order to account for the results; a twist angle of 49° was found.

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