✦ LIBER ✦

1H and 31P NMR spectra of substituted methylphosphonic acids with indirect determination of 31P shifts

✍ Scribed by M. L. Rueppel; J. T. Marvel

Publisher: John Wiley and Sons
Year: 1976
Tongue: English
Weight: 191 KB
Volume: 8
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270080106

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✦ Synopsis

Abstract

Proton and phosphorus magnetic resonance spectra of substituted methylphosphonic acids have been determined as a function of pH. A method has been developed for measuring the ^31^P shift indirectly by optimal heteronuclear decoupling of the ^1^H spectra of samples and standards. Control experiments have demonstrated the broad applicability of this technique to the characterization of low milligram samples of N‐phosphonomethylglycine and potential metabolites.

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