✦ LIBER ✦
Indirect detection of 31P,X connectivities with proton sensitivity: application of two-dimensional 31P-relayed 1H,X correlation spectroscopy
✍ Scribed by Dietrich Gudat
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 246 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.1172
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✦ Synopsis
Abstract
Experiments for ^1^H‐detected heteronuclear ^1^H,X correlation spectroscopy with ^31^P‐relayed coherence transfer are described which allow the indirect detection of δX and ^n^J(X,P) even in the absence of a direct J(X,H) coupling. The use of these techniques for the assignments of ^13^C, ^15^N, and ^183^W NMR data of organophosphorus compounds is demonstrated. Copyright © 2003 John Wiley & Sons, Ltd.