Multiple-quantum proton NMR spectra of the 8-spin system of indene partially oriented in a nematic mesophase were acquired using a magnetic field gradient (MFG) method. Six-, seven-and eight-quantum spectra were solved to yield all intramolecular dipolar couplings (D i j ) which were used to determi
Multiple quantum NMR spectra of toluene and p-bromotoluene partially aligned in a nematic phase
โ Scribed by Leslie D. Field; Saadallah A. Ramadan
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 148 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.1281
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โฆ Synopsis
Abstract
^1^H multiple quantum (MQ) NMR spectra of toluene and pโbromotoluene, partially aligned in a liquid crystalline solvent, were acquired using gradientโassisted methods. The MQ spectra were analysed to give the dipolar couplings (D~ij~) and these were used to determine the molecular shape and average orientation of the of the spin systems. Copyright ยฉ 2003 John Wiley & Sons, Ltd.
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