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1H and 13C assignments of five cembrenes from guggul

✍ Scribed by Shi Bai; Mahendra Jain

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
78 KB
Volume
46
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Chemical shift assignments of ^1^H and ^13^C of five cembrene compounds isolated from the hexane extract of guggul, the resin of Commiphora mukul, are reported. Using ^1^H, ^13^C, and 2D NMR methods their structures were determined as cembrene (1‐isopropyl‐4,8,12‐trimethyl‐cyclotetradeca‐2,4,7,11‐tetraene), cembrene A (1‐isopropenyl‐4,8,12‐trimethyl‐cyclotetradeca‐4,8,12‐triene), cembrenol (1‐isopropyl‐4,8,12‐trimethyl‐cyclotetradeca‐3,7,11‐trienol), mukulol (1‐isopropyl‐4,8,12‐trimethyl‐ cyclotetradeca‐3,7,11‐trienol), and verticillol (4,8,12,15,15‐pentamethyl‐bicyclo[9.3.1]pentadeca‐3,7‐dien‐12‐ol). Copyright © 2008 John Wiley & Sons, Ltd.

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