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17O NMR investigation of phosphite hydrolysis mechanisms

✍ Scribed by Sarah K. McIntyre; Todd M. Alam

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 284 KB
Volume: 45
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.2094

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✦ Synopsis

Abstract

The use of solution ^17^O NMR spectroscopy in verifying the mechanism of trialkyl phosphite hydrolysis is presented. Trimethyl phosphite was reacted with ^17^O‐labeled H~2~O at different temperatures and two reactant concentrations, with the reaction being monitored by ^17^O NMR. Kinetic details elucidated from the NMR spectra are also discussed. Copyright © 2007 John Wiley & Sons, Ltd.

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