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17O NMR spectra of α-diesters

✍ Scribed by Giovanni Cerioni; Gianluca Uccheddu

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
75 KB
Volume
44
Category
Article
ISSN
0749-1581

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✦ Synopsis

Intercarbonyl dihedral angles have been estimated by molecular mechanics, which show invariance except in one case. Because of this invariance, contrary to other a-dicarbonyl compounds, a correlation between chemical shifts and dihedral intercarbonyl angles could not be developed. Spectroscopic and computational results allowed us to evaluate other conformational features.

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