✦ LIBER ✦

1,6:3,4-Dianhydro-2-azido-2-deoxy-β-d-galactopyranose

✍ Scribed by Barnes, John C. ;Brimacombe, John S. ;Paterson, Michael J.

Publisher: International Union of Crystallography
Year: 2002
Tongue: English
Weight: 188 KB
Volume: 58
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536802006931

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, C 6 H 7 N 3 O 3 , the presence of the epoxide group modi®es the bonding in the sugar ring so that the ®ve C atoms within it are coplanar, with a shortening of the formally single CÐC bonds to an average of 1.475 (8) A Ê .

📜 SIMILAR VOLUMES

Crystal and molecular structure of 1,6:3

Crystal and molecular structure of 1,6:3,4-dianhydro-2-O-p-tolylsulfonyl-β-d-galactopyranose

✍ An-Lai Wang; Shi-Jie Lu; Hong-Xiang Fu; Han-Qing Wang; Xiao-Ying Huang 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 380 KB

The opening ot" oxirane rings o1' dianhydro sugars with high regiosclectivily can afford many chiral intermediates Ibr controlling asymmetric syntheses [I-5]. Here, wc report the crystal structure o1' 1,6:3,4~diallhydro-2-Ool~-lolylsullbnyl-~-D°galactopyranose (!) which may provide helpl'ul i111' o1

1,6-Anhydro-2-iodo-2-deoxy-β-d-glucopy

1,6-Anhydro-2-iodo-2-deoxy-β-d-glucopyranose (Iodolevoglucosan)

✍ Gehle, Dietmar ;Flörke, Ulrich ;Krohn, Karsten 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 253 KB

The molecular structure of the title compound, C 6 H 9 IO 4 , is similar to that of 1,6-anhydro--d-glucopyranose. The crystal packing shows strong intermolecular O-HÁ Á ÁO and C-HÁ Á ÁI hydrogen bonds.

Synthesis of benzyl 2-azido-2-deoxy-4-O-

Synthesis of benzyl 2-azido-2-deoxy-4-O-β-d-glucopyranosyl-α-d-glucopyranoside and 1,6-anhydro-2-azido-2-deoxy-4-O-β-d-glucopyranosyl-β-d-glucopyranose

✍ Tony K.M. Shing; Arthur S. Perlin 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 725 KB

Improved preparation of 1,6-anhydro-4-de

Improved preparation of 1,6-anhydro-4-deoxy-2-O-p-toluenesulphonylβ-d-xylo-hexopyranose and of its d-[4-2H]gluco-analogue from 1,6 : 3,4-dianhydro-2-O-p-toluenesulphonyl-β-d-galactopyranose

✍ Tomáš Trnka; Miloš Buděšínský; Miloslav Černý 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 262 KB

6-O-Cyanomethyl-1,2:3,4-di-O-isopropyl

6-O-Cyanomethyl-1,2:3,4-di-O-isopropylidene-α-d-galactopyranose

✍ Langer, Vratislav ;Steiner, Bohumil ;Mičová, Júlia ;Koóš, Miroslav 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 194 KB

3-Azido-3-deoxy-2,2′:5,6-di-O-isopropyl

3-Azido-3-deoxy-2,2′:5,6-di-O-isopropylidene-2-C-hydroxmethyl-d-gulono-1,4-lactone

✍ Harding, Christopher C. ;Shallard-Brown, Howard ;Watkin, David J. ;Soengas, Raqu 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 897 KB

Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.005 A Ê R factor = 0.045 wR factor = 0.108 Data-to-parameter ratio = 9.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

1,6:3,4-Dian­hydro-2-azido-2-deoxy-β-d-galactopyran­ose

✦ Synopsis

1,6:3,4-Dianhydro-2-azido-2-deoxy-β-d-galactopyranose