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1,6-An­hydro-2-iodo-2-deoxy-β-d-gluco­pyran­ose (Iodo­levoglucosan)

✍ Scribed by Gehle, Dietmar ;Flörke, Ulrich ;Krohn, Karsten


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
253 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The molecular structure of the title compound, C 6 H 9 IO 4 , is similar to that of 1,6-anhydro--d-glucopyranose. The crystal packing shows strong intermolecular O-HÁ Á ÁO and C-HÁ Á ÁI hydrogen bonds.


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In the title compound, C 6 H 7 N 3 O 3 , the presence of the epoxide group modi®es the bonding in the sugar ring so that the ®ve C atoms within it are coplanar, with a shortening of the formally single CÐC bonds to an average of 1.475 (8) A Ê .