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1,6-Anhydro-2,3-di-O-methyl-β-L-idopyranose and 1,6-Anhydro-2,3,4-tri-O-methyl-β-L-idopyranose 1

✍ Scribed by Baggett, Neil; Stoffyn, Pierre J.; Jeanloz, Roger W.


Book ID
126471541
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
538 KB
Volume
28
Category
Article
ISSN
0022-3263

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Synthesis of 1,6-anhydro-2,3-di-O-benzoy
✍ Yoshitaka Ichikawa; Hiroyoshi Kuzuhara 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 986 KB

The title compound (21) was synthesized from cellobiose as a synthon of a heparin-related oligosaccharide. The per-0-benzyl and per-0-benzoyl derivatives of 1 ,6-anhydro-4-0-(6-deoxy-B-D-~~~lo-hex-5-enopyranosyl)-~-~-glucopyranose were treated with a nonsolvated borane to give a 1 :2 mixture of the