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1,6-Anhydro-1-thio-β-D-glucopyranose (Thiolevoglucosan) and the Corresponding Sulfoxides and Sulfone

✍ Scribed by Buděšínský, Miloš; Poláková, Jana; Hamerníková, Michaela; Císařová, Ivana; Trnka, Tomáš; Černý, Miloslav


Book ID
115548354
Publisher
UOCHB
Year
2006
Tongue
English
Weight
402 KB
Volume
71
Category
Article
ISSN
0010-0765

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✍ Adrie J.J. Straatho; Johannes M. Vrolijk; Herman van Bekkum; Antonius P.G. Kiebo 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 379 KB

The sulfuric acid-catalysed reaction of 1,6-anhydro+D-glucopyranose in lbutanol at SO" gave butyl a-and P-D-glucopyranoside as the sole products. The initial kinetic alp ratio was 1.5, and the final a//3 ratio upon equilibration was 2.7. The four pseudo-first-order reaction rate constants involved h