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1,5-Diazabicyclo[3.1.0]hexanes and 1,6-diazabicyclo[4.1.0]heptanes: a new method for the synthesis, quantum-chemical calculations, and X-ray diffraction study

✍ Scribed by V.V. Kuznetsov; S.A. Kutepov; N.N. Makhova; K.A. Lyssenko; D.E. Dmitriev


Book ID
111537780
Publisher
Springer
Year
2003
Tongue
English
Weight
464 KB
Volume
52
Category
Article
ISSN
1573-9171

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ChemInform Abstract: Stereospecific Synt
✍ S. N. DENISENKO; P. RADEMACHER; R. G. KOSTYANOVSKY πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

## Stereospecific Synthesis of Bicyclic Diaziridines: 4a-Chloro-; 4e,6a-and 4a,6e-Dichloro-5-methoxycarbonyl-1,6diazabicyclo[3.1.0]hexanes. -Amination of 3-chloro-1-pyrroline (I) with H 2 N-O-SO 3 H occurs predominantly from the anti side with respect to chlorine to afford diaziridine (II). Chlor