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Molecular Structure of 1,5-Diazabicyclo[3.1.0]hexane as Determined by Gas Electron Diffraction and Quantum-Chemical Calculations

✍ Scribed by Vishnevskiy, Yuri V.; Vogt, Natalja; Vogt, Jürgen; Rykov, Anatolii N.; Kuznetsov, Vladimir V.; Makhova, Nina N.; Vilkov, Lev V.


Book ID
120440517
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
487 KB
Volume
112
Category
Article
ISSN
1089-5639

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✍ Yuri V. Vishnevskiy; Maxim A. Abaev; Arkadii A. Ivanov; Lev V. Vilkov; Marwan Da 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 372 KB

The molecular structure and conformation of tris(cyclopropylsilyl)amine (TCPSA) has been studied by means of gas-phase electron diffraction at 338 K and quantum-chemical calculations. A total of 12 relatively stable conformations of TCPSA molecule were considered. According to the experimental resul