The title compound, C 25 H 29 NO 3 , was prepared from (R)-5,5dimethyl-4-phenyl-3-[(E)-3-phenylacryloyl]oxazolidin-2-one, coupled with cyclopentylmagnesium bromide via asymmetric Michael addition. The relative configuration of the chiral C atoms of the product is as expected.
✦ LIBER ✦
1,4-Diphenyl-2,3-dithien-3-ylcyclopentadien-1-one
✍ Scribed by Linehan, Justin ;Crundwell, Guy ;Herron, Steven R. ;Kantardjieff, Katherine A.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 215 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
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View of the molecule of (I), showing the atom-labeling scheme. Displacement ellipsoids are drawn at the 30% probability level.
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In the title compound, C 18 H 23 NS 2 , the bond lengths and angles are unexceptional. The butyl chain is in a fully extended conformation. The dihedral angle between the thiazole and phenyl rings is 87.21 (2) . The crystal structure is stabilized by one weak intramolecular C-HÁ Á ÁS hydrogen bond.