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13C NMR study of N-unsubstituted aziridines: I—steric effects, pseudoconjugation

✍ Scribed by P. Mison; R. Chaabouni; Y. Diab; R. Martino; A. Lopez; A. Lattes; F. W. Wehrli; T. Wirthlin

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
717 KB
Volume
8
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

^13^C chemical shifts for twenty‐nine alkyl and phenyl substituted N‐unsubstituted aziridines have been measured. Additivity parameters for methyl, phenyl and aziridyl carbons have been derived with the aim of testing the consistency of the assignments made on the basis of chemical shift considerations and off‐resonance decoupling information. The observed chemical shifts are discussed in terms of steric and pseudoconjugation effects.

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