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13C NMR Studies: Effect of steric compression on chemical shifts of carbons in diastereoisomers

✍ Scribed by Mahavir Prashad; M. Seth; A. P. Bhaduri; Avijit Banerji


Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
148 KB
Volume
14
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

^13^C NMR of diastereoisomeric pairs of 2,3‐diaryl‐2‐methylbutyronitriles revealed a difference in the chemical shift of the carbon atoms between the diastereoisomers and the observed shifts were greatly influenced by the presence of an ortho substituent in the 3‐phenyl ring.


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