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13C and 15N NMR study of acyclic vicinal diastereoisomers. Conformational effects

✍ Scribed by George C. Levy; T. Pehk; E. Lippmaa

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
568 KB
Volume
14
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Conformations of aliphatic diastereoisomers with vicinal asymmetric centers (2,3‐disubstituted butanes and 5,6‐disubstituted n‐decanes) are discussed in terms of their ^13^C and, in some cases, ^15^N chemical shifts and spin‐lattice relaxation times. Solvent and protonation effects are explained by conformational changes in the isomers.

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