13C NMR spectral data for nine tetrahydro-1.5-benzodiazepin-2-ones are reported and the chemical shift assignments are discussed. The steric energies of the E and Z isomers of formyl derivatives were estimated by computer molecular modeling
13C NMR Study of Dihydropyrimidinedione and Dihydropyrimidine-2-thione Derivatives
✍ Scribed by K. BERESNEVIČIŪTĖ; Z. BERESNEVIČIUS; G. MIKULSKIENĖ; J. KIHLBERG; J. BRODDEFALK
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 211 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
The 13C NMR spectral data for 18 dihydropyrimidinediones and their 2-thio analogues are presented. The influence of substituents on the shielding of neighbouring atoms was analysed and the resonances were unambiguously assigned. 13C NMR spectroscopy was shown to be useful for structural determination of dihydropyrimidinediones and thioanalogues and allowed the facile distinction of otherwise similar compounds from the two classes. 1997
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