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13C isotope effect on the reaction catalyzed by prephenate dehydratase

โœ Scribed by Jeremy Van Vleet; Andreas Kleeb; Peter Kast; Donald Hilvert; W.W. Cleland

Book ID
103823629
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
209 KB
Volume
1804
Category
Article
ISSN
1570-9639

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## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 ยฑ 2 K and 1013 ยฑ 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~