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13C and 2H Kinetic Isotope Effects and the Mechanism of Lewis Acid-Catalyzed Ene Reactions of Formaldehyde

✍ Scribed by Singleton, Daniel A.; Hang, Chao

Book ID
115473512
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
114 KB
Volume
65
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Lewis Acid Catalyzed Additions to Unsatu
Lewis Acid Catalyzed Additions to Unsaturated Fatty Compounds. II: Alkylaluminium Halide Catalyzed Ene Reactions of Unsaturated Fatty Compounds and Formaldehyde
✍ Biermann, Ursula ;Metzger, J. O. πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons βš– 282 KB

We are presenting our results on the alkylaluminium halide catalyzed ene addition of formaldehyde to readily available unsaturated fatty compounds to give primary homoallylic alcohols. The reaction of oleic acid and 10-undecenoic acid with formaldehyde gives (E)-S(lO)-(hydroxyrneth~ yI)octadec-l0(8)