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13C - 199Hg spin coupling in alkylmercurials : A useful angular dependence of vicinal coupling

✍ Scribed by William Kitching; David Praeger; David Doddrell; F.A.L. Anet; Jostein Krane


Book ID
104213518
Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
176 KB
Volume
16
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


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## Abstract A series of alicyclic compounds with dihedral angles of 0Β°, 60Β°, 90Β°, 120Β° and 180Β° between a ^13^C‐labelled carbon atom and a carbon atom separated by three bonds from the label has been synthesized. The vicinal ^13^C^13^C spin coupling constants were measured, and from the results a K

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## Abstract The magnitude of the NMR spin‐spin coupling constant, ^3^__J__(CH), between a vicinal ^13^C–^1^H pair depends, __inter alia__, on the value of the torsion angle Ξ¦~CH~(^13^Cο£ΏCο£ΏCο£ΏH) and is influenced by the presence of an electronegative substituent located on the coupling ^13^C nucleus.