Angular dependence of vicinal hydrogen-1-nitrogen-14 spin coupling
β Scribed by Terui, Yoshihiro.; Aono, Katsutoshi.; Tori, Kazuo.
- Book ID
- 126062714
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 277 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract An approximate KarplusβConroy relationship between the vicinal coupling constants __J__(HSiCH) in a silaethane fragment and the corresponding torsional angles Ο in silacyclohexanes is proposed. The relationship ^3^__J__(HSiCH) VS Ο is asymmetric. The ^1^H NMR parameters and conformation
## Abstract A series of organic phosphonate and hydroxyβphosphonate derivatives have been synthesised and their NMR spectra fully analysed. The __vicinal__ ^31^Pο£Ώ^1^H coupling constants of these derivatives give evidence of a regular angular dependence.