1,3-Dipolar Cycloaddition of Nitriles under Microwave Irradiation in Solvent-Free Conditions
✍ Scribed by Díaz-Ortiz, Angel; Díez-Barra, Enrique; de la Hoz, Antonio; Moreno, Andrés; J. Gómez-Escalonilla, Maria; Loupy, André
- Book ID
- 115460101
- Publisher
- Japan Institute of Heterocyclic Chemistry
- Year
- 1996
- Tongue
- English
- Weight
- 221 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0385-5414
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Aldoximes and ketoximes were readily synthesized from aldehydes and hydroxylamine hydrochloride on Al 2 O 3 without solvent under microwave irradiation. At higher irradiation power, aldoximes dehydrated to nitriles and ketoximes rearranged to amides. Aldoximes reacted in a one-pot reaction with Nchl
Synthesis of Oximes, Conversion to Nitrile Oxides and Their Subsequent 1,3-Dipolar Cycloaddition Reactions under Microwave Irradiation and Solvent-Free Reaction Conditions. -Aldoximes and ketoximes (II) are readily synthesized from aldehydes and ketones (I) on Al 2 O 3 under microwave irradiation.