1,3-dipolar cycloaddition of nitrile oxides with 2-phenyl-4-ethoxymethylene-5(4H)-oxazolone
β Scribed by E. Coutouli-Argyropoulou; E. Thessalonikeos
- Book ID
- 112130270
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1992
- Tongue
- English
- Weight
- 206 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0022-152X
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π SIMILAR VOLUMES
4,5-Dihydro-2-methyloxazole la and 4,5-dihydro-2,4.4-trimethyloxazole lb, which are examples of cyclic imidate esters, undergo 1,fdipolar cycloaddition reactions with benzonitrile N-oxide, to give the appropriate 5,6-dihydro-7a-methyl-3-
## Abstract Nitrile oxides 2a, b and nitrile imines 2cβe are added to the C ο£Ύ C bond of 4βarylideneβ2βphenylβ5(4__H__)βthiazolones 1 to afford spiroβisoxazolines 3aβd and spiroβpyrazolines 3eβj, respectively. The cycloaddition reactions are regioselective and only one of the two possible regioisome