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13 C Kinetic Isotope Effect of the Pudovik Reaction

✍ Scribed by Wiktorowicz, Justyna; Jankowski, Stefan

Book ID
127224636
Publisher
Taylor and Francis Group
Year
2014
Tongue
English
Weight
230 KB
Volume
189
Category
Article
ISSN
1042-6507

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✍ Karen L. Feilberg; David W. T. Griffith; Matthew S. Johnson; Claus J. Nielsen πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 134 KB πŸ‘ 1 views

## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 Β± 2 K and 1013 Β± 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~