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1,3-bis(4-ethynylbenzoyl)benzene

โœ Scribed by Georges Lucotte; Bruno Delfort


Publisher
Springer
Year
1991
Tongue
English
Weight
224 KB
Volume
26
Category
Article
ISSN
0170-0839

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A new flexible bis(pyridyl) complex, C~18~H~18~N~4~, was prepared by the reaction of terephthalaldehyde with 3-aminopyridine. The molecule is centrosymmetric. Mononuclear units are linked into a one-dimensional chain by intermolecular Nโ€”H...N hydrogen bonds. The dihedral angle bentween the pyridyl r

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The title compound, C 24 H 38 N 4 O 4 , was synthesized by the reaction of terephthalaldehyde and morpholine in ethanol. The N atoms of the four morpholine rings are bonded to benzyl C atoms, forming a centrosymmetric 1,4-bis(dimorpholinomethyl)benzene molecule.

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The complete molecule of the title compound, C~18~H~18~N~4~, is generated by crystallographic twofold rotation symmetry, with two C atoms lying on the rotation axis. The pair of pyridyl rings form a dihedral angle of 78.4โ€…(2)ยฐ and the dihedral angle between the pyridyl ring and the central benzene r