A new flexible bis(pyridyl) complex, C~18~H~18~N~4~, was prepared by the reaction of terephthalaldehyde with 3-aminopyridine. The molecule is centrosymmetric. Mononuclear units are linked into a one-dimensional chain by intermolecular N—H...N hydrogen bonds. The dihedral angle bentween the pyridyl r
✦ LIBER ✦
1,3-Bis(2-pyridylaminomethyl)benzene
✍ Scribed by Zhu, Li-Na ;Gao, Shan ;Huo, Li-Hua
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 320 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The complete molecule of the title compound, C~18~H~18~N~4~, is generated by crystallographic twofold rotation symmetry, with two C atoms lying on the rotation axis. The pair of pyridyl rings form a dihedral angle of 78.4 (2)° and the dihedral angle between the pyridyl ring and the central benzene ring is 110.4 (2)°. The molecules are linked into a one-dimensional chain by N—H...N hydrogen bonds.
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