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1,3-Bis(2-pyridylaminomethyl)benzene

✍ Scribed by Zhu, Li-Na ;Gao, Shan ;Huo, Li-Hua


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
320 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The complete molecule of the title compound, C~18~H~18~N~4~, is generated by crystallographic twofold rotation symmetry, with two C atoms lying on the rotation axis. The pair of pyridyl rings form a dihedral angle of 78.4 (2)° and the dihedral angle between the pyridyl ring and the central benzene ring is 110.4 (2)°. The molecules are linked into a one-dimensional chain by N—H...N hydrogen bonds.


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1,4-Bis(3-pyridylaminomethyl)benzene
✍ Zhu, Li-Na ;Gao, Shan ;Huo, Li-Hua 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 250 KB

A new flexible bis(pyridyl) complex, C~18~H~18~N~4~, was prepared by the reaction of terephthalaldehyde with 3-aminopyridine. The molecule is centrosymmetric. Mononuclear units are linked into a one-dimensional chain by intermolecular N—H...N hydrogen bonds. The dihedral angle bentween the pyridyl r

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