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1,2,4-Triazolo[1,5-a]pyrimidin-3-ium chloride

✍ Scribed by Maldonado, Carmen R. ;Quirós, Miguel ;Salas, Juan M.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
189 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The cation of the title molecule, C~5~H~5~N~4~
^+^·Cl^−^, is strictly planar; it occupies a special position on a mirror plane. The protonation of the heterocycle takes place, as expected, at an N atom of the imidazole ring. This H atom is hydrogen bonded to the chloride anion.


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1,2,3-Triazolo[4,5-e]-1,2,4-triazolo[3,4
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## Abstract Some new 1,2,3‐triazolo[4,5‐__e__]‐1,2,4‐triazolo[3,4‐__c__]pyrimidmes were prepared starting from the corresponding 1,2,3‐triazolo[4,5‐__d__]pyrimidines __via__ the formation of the 1,2,4‐triazole ring. Thus suitable hydrazino derivatives 6 were condensed with triethyl orthoformate, tr

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## Abstract The condensation of malonoaldehyde derivatives with either a 3‐amino‐[1,2,4]‐triazole or a 3,5‐diamino‐[1,2,4]‐triazole precursor was studied. In agreement with previous reports, two different bicycles, namely, bearing the regioisomeric [1,2,4]triazolo[1,5‐a]pyrimidine (**1**) or[1,2,4]