## Abstract Some new 1,2,3‐triazolo[4,5‐__e__]‐1,2,4‐triazolo[3,4‐__c__]pyrimidmes were prepared starting from the corresponding 1,2,3‐triazolo[4,5‐__d__]pyrimidines __via__ the formation of the 1,2,4‐triazole ring. Thus suitable hydrazino derivatives 6 were condensed with triethyl orthoformate, tr
1,2,4-Triazolo[1,5-a]pyrimidin-3-ium chloride
✍ Scribed by Maldonado, Carmen R. ;Quirós, Miguel ;Salas, Juan M.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 189 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The cation of the title molecule, C~5~H~5~N~4~
^+^·Cl^−^, is strictly planar; it occupies a special position on a mirror plane. The protonation of the heterocycle takes place, as expected, at an N atom of the imidazole ring. This H atom is hydrogen bonded to the chloride anion.
📜 SIMILAR VOLUMES
## Abstract The 7‐chloro‐3‐(2‐chlorobenzyl)‐ and 7‐chloro‐3‐(2‐fluorobenzyl)‐1,2,3‐triazolo[4,5‐__d__]pyrimidines (**1** and **4**), by nucleophilic replacement with some hydrazides, gave the corresponding 7‐hydrazidoderivatives (**2a‐e** and **5a‐e**). These, by heating in Dowtherm, underwent an i
## Abstract The condensation of malonoaldehyde derivatives with either a 3‐amino‐[1,2,4]‐triazole or a 3,5‐diamino‐[1,2,4]‐triazole precursor was studied. In agreement with previous reports, two different bicycles, namely, bearing the regioisomeric [1,2,4]triazolo[1,5‐a]pyrimidine (**1**) or[1,2,4]