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1,2,3-Benzodithiazolyl radicals formed by thermolysis and photolysis of 1,3,2,4-benzodithiadiazines

โœ Scribed by Vlasyuk, Ivan V.; Bagryansky, Victor A.; Gritsan, Nina P.; Molin, Yuri N.; Yu. Makarov, Alexander; Gatilov, Yuri V.; Shcherbukhin, Vladimir V.; Zibarev, Andrey V.

Book ID
120369950
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
185 KB
Volume
3
Category
Article
ISSN
1463-9076

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โœ J.E. Franz; L.L. Black ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 189 KB

The thermolysis and photolysis of various oxazoles, diazoles and triazoles 1 have'been reported (la,lb) to generate labile 1,3-dipoles (nitrenes) z which subsequently rearrange to cumulene structures 3 or react with certain dipolar-ophiles (when present) to yield 1,3-dipolar adducts 4. Z=