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Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines

✍ Scribed by Victor A. Bagryansky; Ivan V. Vlasyuk; Yuri V. Gatilov; Alexander Yu. Makarov; Yuri N. Molin; Vladimir V. Shcherbukhin; Andrey V. Zibarev


Book ID
119981351
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
128 KB
Volume
10
Category
Article
ISSN
0959-9436

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## Abstract In contrast to thermolysis of 1,3Ξ»^4^Ξ΄^2^,2,4‐benzodithiadiazine (**1**) and its 5,6,7,8‐tetrafluoro derivative **2** in dilute (10^–3^ M) hydrocarbon solutions, which leads to persistent 1,2,3‐benzodithiazolyls in nearly quantitative yields, the thermolysis of **1** and **2** (the 6‐6