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1,2-dimagnesium derivatives of cyclopropane

✍ Scribed by J.W.F.L. Seetz; O.S. Akkerman; F. Bickelhaupt

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
209 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis

cis-1,2-Dibromomagnesiocyclopropane (cis-f) was isolated from the reaction Of both trams-and cis-1,2_dibromocyclopropane

(A) with magnesium. The corresponding dialkylmag nesium species (I), an oligomer of 2-magnesabicyclobutae, was obtained from cis-4 by precipitation in THF; it forms a soluble complex 8 with MgBr2.

In 1960, Wiberg and Bartley' reacted trans-1,2_dibromocyclopropane (trans-2) with magnesium and observed, on treatment of the reaction mixture with CO2 or D20, the formation of 2 and 2,

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