1,2-Bis(diphenylthioarsinoyl)ethane
✍ Scribed by Davies, Sian C. ;Smith, Matt C. ;Evans, David J.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 337 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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The crystal structure of the title compound, [(dppe-P,P H )Cu-(dppeS-P)(SC{O}Ph)], [Cu(C 7 H 5 OS)(C 26 H 24 P 2 S)(C 26 H 24 P 2 )], is reported. In this monomeric compound, the Cu atom has a tetrahedral coordination geometry, with a P 3 CuS core.
In the title crystal structure, C 14 H 14 S 2 , L 2 , the molecules lie on crystallographic inversion centers. The phenyl rings are nearly perpendicular to the planar S-C-C-S group of atoms.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.051 wR factor = 0.130 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.